Bismuth

Bismuth, ₈₃Bi

Bismuth
Pronunciation	/ˈbɪzməθ/ ​(BIZ-məth)
Appearance	lustrous brownish silver
Standard atomic weight Ar°(Bi)
	208.98040±0.00001[1] 208.98±0.01 (abridged)[2]
Bismuth in the periodic table
Hydrogen Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson Sb ↑ Bi ↓ Mc lead ← bismuth → polonium
Atomic number (Z)	83
Group	group 15 (pnictogens)
Period	period 6
Block	p-block
Electron configuration	[Xe] 4f14 5d10 6s2 6p3
Electrons per shell	2, 8, 18, 32, 18, 5
Physical properties
Phase at STP	solid
Melting point	544.7 K ​(271.5 °C, ​520.7 °F)
Boiling point	1837 K ​(1564 °C, ​2847 °F)
Density (at 20° C)	9.807 g/cm3 [3]
when liquid (at m.p.)	10.05 g/cm3
Heat of fusion	11.30 kJ/mol
Heat of vaporization	179 kJ/mol
Molar heat capacity	25.52 J/(mol·K)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 941 1041 1165 1325 1538 1835
Atomic properties
Oxidation states	−3, −2, −1, 0,[4] +1, +2, +3, +4, +5 (a mildly acidic oxide)
Electronegativity	Pauling scale: 2.02
Ionization energies	1st: 703 kJ/mol 2nd: 1610 kJ/mol 3rd: 2466 kJ/mol (more)
Atomic radius	empirical: 156 pm
Covalent radius	148±4 pm
Van der Waals radius	207 pm
Spectral lines of bismuth
Other properties
Natural occurrence	primordial
Crystal structure	​rhombohedral (hR2)
Lattice constants	a = 0.47458 nm α = 57.236° ah = 0.45462 nm ch = 1.18617 nm (at 20 °C)[3]
Thermal expansion	13.09×10−6/K (at 20 °C)[a]
Thermal conductivity	7.97 W/(m⋅K)
Electrical resistivity	1.29 µΩ⋅m (at 20 °C)
Magnetic ordering	diamagnetic
Molar magnetic susceptibility	−280.1×10−6 cm3/mol[5]
Young's modulus	32 GPa
Shear modulus	12 GPa
Bulk modulus	31 GPa
Speed of sound thin rod	1790 m/s (at 20 °C)
Poisson ratio	0.33
Mohs hardness	2.25
Brinell hardness	70–95 MPa
CAS Number	7440-69-9
History
Discovery	Arabic alchemists (before AD 1000)
Isotopes of bismuth v e
Main isotopes[6] Decay abun­dance half-life (t1/2) mode pro­duct 207Bi synth 31.55 y β+ 207Pb 208Bi synth 3.68×105 y β+ 208Pb 209Bi 100% 2.01×1019 y α 205Tl 210Bi trace 5.012 d β− 210Po α 206Tl 210mBi synth 3.04×106 y α 206Tl
Category: Bismuth view talk edit | references

Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Bismuth was long considered the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was discovered to be extremely weakly radioactive. The metal's only primordial isotope, bismuth-209, undergoes alpha decay with a half-life about a billion times the estimated age of the universe.^[7][8]

Bismuth metal has been known since ancient times. Before modern analytical methods bismuth's metallurgical similarities to lead and tin often led it to be confused with those metals. The etymology of "bismuth" is uncertain. The name may come from mid-sixteenth century Neo-Latin translations of the German words weiße Masse or Wismuth, meaning 'white mass', which were rendered as bisemutum or bisemutium.

Bismuth compounds account for about half the global production of bismuth. They are used in cosmetics; pigments; and a few pharmaceuticals, notably bismuth subsalicylate, used to treat diarrhea.^[8] Bismuth's unusual propensity to expand as it solidifies is responsible for some of its uses, as in the casting of printing type.^[8] Bismuth, when in its elemental form, has unusually low toxicity for a heavy metal.^[8] As the toxicity of lead and the cost of its environmental remediation became more apparent during the 20th century, suitable bismuth alloys have gained popularity as replacements for lead. Presently, around a third of global bismuth production is dedicated to needs formerly met by lead.

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