Carbon nanobud

Computer models of several stable nanobud structures

In situ observation of a carbon nanobud by transmission electron microscopy^[1]

Capture of an additional fullerene molecule by a nanobud^[1]

Generation of fullerene molecules (carbon peapod) inside a nanobud^[1]

In nanotechnology, a carbon nanobud is a material that combines carbon nanotubes and spheroidal fullerenes, both allotropes of carbon, forming "buds" attached to the tubes. Carbon nanobuds were discovered and synthesized in 2006.^[2]

In this material, fullerenes are bonded with covalent bonds to the outer sidewalls of the underlying nanotube. Consequently, nanobuds exhibit properties of carbon nanotubes and fullerenes. The mechanical properties and the electrical conductivity of the nanobuds are similar to those of carbon nanotubes.^[3]^[4]^[5]

Canatu Oy, a Finnish company, claims the intellectual property rights for nanobuds, its synthesis processes, and several applications.^[6]

^ ^a ^b ^c Gorantla, Sandeep; Börrnert, Felix; Bachmatiuk, Alicja; Dimitrakopoulou, Maria; Schönfelder, Ronny; Schäffel, Franziska; Thomas, Jürgen; Gemming, Thomas; Borowiak-Palen, Ewa; Warner, Jamie H.; Yakobson, Boris I.; Eckert, Jürgen; Büchner, Bernd; Rümmeli, Mark H. (2010). "In situ observations of fullerene fusion and ejection in carbon nanotubes". Nanoscale. 2 (10): 2077–2079. Bibcode:2010Nanos...2.2077G. doi:10.1039/C0NR00426J. PMID 20714658.
^ Nasibulin, Albert G.; Pikhitsa, Peter V.; Jiang, Hua; Brown, David P.; Krasheninnikov, Arkady V.; Anisimov, Anton S.; Queipo, Paula; Moisala, Anna; Gonzalez, David; Lientschnig, Günther; Hassanien, Abdou (March 2007). "A novel hybrid carbon material". Nature Nanotechnology. 2 (3): 156–161. Bibcode:2007NatNa...2..156N. doi:10.1038/nnano.2007.37. ISSN 1748-3395. PMID 18654245.
^ Nasibulin, Albert G.; et al. (2007). "A novel hybrid carbon material" (PDF). Nature Nanotechnology. 2 (3): 156–161. Bibcode:2007NatNa...2..156N. doi:10.1038/nnano.2007.37. PMID 18654245. Archived from the original (PDF) on 26 February 2012. Retrieved 31 August 2009.
^ Nasibulin, Albert G.; et al. (2007). "Investigations of NanoBud formation" (PDF). Chemical Physics Letters. 446 (1–3): 109–114. Bibcode:2007CPL...446..109N. doi:10.1016/j.cplett.2007.08.050. Archived from the original (PDF) on 20 July 2011. Retrieved 31 August 2009.
^ Fürst, Joachim A.; et al. (2009). "Electronic transport properties of fullerene functionalized carbon nanotubes: Ab initio and tight-binding calculations" (PDF). Physical Review B. 80 (3): 115117. Bibcode:2009PhRvB..80c5427F. doi:10.1103/PhysRevB.80.035427. S2CID 7334189.
^ "European Patent Office: search CANATU". Retrieved 3 June 2010.

[r1-1] Gorantla, Sandeep; Börrnert, Felix; Bachmatiuk, Alicja; Dimitrakopoulou, Maria; Schönfelder, Ronny; Schäffel, Franziska; Thomas, Jürgen; Gemming, Thomas; Borowiak-Palen, Ewa; Warner, Jamie H.; Yakobson, Boris I.; Eckert, Jürgen; Büchner, Bernd; Rümmeli, Mark H. (2010). "In situ observations of fullerene fusion and ejection in carbon nanotubes". Nanoscale. 2 (10): 2077–2079. Bibcode:2010Nanos...2.2077G. doi:10.1039/C0NR00426J. PMID 20714658.

[2] Nasibulin, Albert G.; Pikhitsa, Peter V.; Jiang, Hua; Brown, David P.; Krasheninnikov, Arkady V.; Anisimov, Anton S.; Queipo, Paula; Moisala, Anna; Gonzalez, David; Lientschnig, Günther; Hassanien, Abdou (March 2007). "A novel hybrid carbon material". Nature Nanotechnology. 2 (3): 156–161. Bibcode:2007NatNa...2..156N. doi:10.1038/nnano.2007.37. ISSN 1748-3395. PMID 18654245.

[Nasibulin-3] Nasibulin, Albert G.; et al. (2007). "A novel hybrid carbon material" (PDF). Nature Nanotechnology. 2 (3): 156–161. Bibcode:2007NatNa...2..156N. doi:10.1038/nnano.2007.37. PMID 18654245. Archived from the original (PDF) on 26 February 2012. Retrieved 31 August 2009.

[4] Nasibulin, Albert G.; et al. (2007). "Investigations of NanoBud formation" (PDF). Chemical Physics Letters. 446 (1–3): 109–114. Bibcode:2007CPL...446..109N. doi:10.1016/j.cplett.2007.08.050. Archived from the original (PDF) on 20 July 2011. Retrieved 31 August 2009.

[5] Fürst, Joachim A.; et al. (2009). "Electronic transport properties of fullerene functionalized carbon nanotubes: Ab initio and tight-binding calculations" (PDF). Physical Review B. 80 (3): 115117. Bibcode:2009PhRvB..80c5427F. doi:10.1103/PhysRevB.80.035427. S2CID 7334189.

[6] "European Patent Office: search CANATU". Retrieved 3 June 2010.

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