Carbon nanotube

A scanning tunneling microscopy image of a single-walled carbon nanotube
A greyscale microscope image showing a rigid rod extending from both sides of a mottled cellular mass
A scanning electron microscope image of bundles of multiwalled carbon nanotube piercing an alveolar epithelial cell.
Rotating single-walled zigzag carbon nanotube

A carbon nanotube (CNT) is a tube made of carbon with a diameter in the nanometre range (nanoscale). They are one of the allotropes of carbon.

Single-walled carbon nanotubes (SWCNTs) have diameters around 0.5–2.0 nanometres, about 100,000 times smaller than the width of a human hair. They can be idealised as cutouts from a two-dimensional graphene sheet rolled up to form a hollow cylinder.[1]

Multi-walled carbon nanotubes (MWCNTs) consist of nested single-wall carbon nanotubes[1] in a nested, tube-in-tube structure.[2] Double- and triple-walled carbon nanotubes are special cases of MWCNT.

Carbon nanotubes can exhibit remarkable properties, such as exceptional tensile strength[3] and thermal conductivity[4][5][6] because of their nanostructure and strength of the bonds between carbon atoms. Some SWCNT structures exhibit high electrical conductivity[7][8] while others are semiconductors.[9][10] In addition, carbon nanotubes can be chemically modified.[11] These properties are expected to be valuable in many areas of technology, such as electronics, optics, composite materials (replacing or complementing carbon fibres), nanotechnology (including nanomedicine[12]), and other applications of materials science.

The predicted properties for SWCNTs were tantalising, but a path to synthesising them was lacking until 1993, when Iijima and Ichihashi at NEC, and Bethune and others at IBM independently discovered that co-vaporising carbon and transition metals such as iron and cobalt could specifically catalyse SWCNT formation.[13][14] These discoveries triggered research that succeeded in greatly increasing the efficiency of the catalytic production technique,[15] and led to an explosion of work to characterise and find applications for SWCNTs.

  1. ^ a b Cite error: The named reference Iijima1 was invoked but never defined (see the help page).
  2. ^ Cite error: The named reference endo1 was invoked but never defined (see the help page).
  3. ^ Cite error: The named reference Strength and Breaking was invoked but never defined (see the help page).
  4. ^ Sadri R, Ahmadi G, Togun H, Dahari M, Kazi SN, Sadeghinezhad E, et al. (28 March 2014). "An experimental study on thermal conductivity and viscosity of nanofluids containing carbon nanotubes". Nanoscale Research Letters. 9 (1): 151. Bibcode:2014NRL.....9..151S. doi:10.1186/1556-276X-9-151. PMC 4006636. PMID 24678607.
  5. ^ Cite error: The named reference Bever was invoked but never defined (see the help page).
  6. ^ Cite error: The named reference Kim was invoked but never defined (see the help page).
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  8. ^ Cite error: The named reference Tans was invoked but never defined (see the help page).
  9. ^ Cite error: The named reference Hamada was invoked but never defined (see the help page).
  10. ^ Cite error: The named reference wildoer was invoked but never defined (see the help page).
  11. ^ Cite error: The named reference Karousis-2010 was invoked but never defined (see the help page).
  12. ^ Sharma M, Alessandro P, Cheriyamundath S, Lopus M (2024). "Therapeutic and diagnostic applications of carbon nanotubes in cancer: recent advances and challenges". Journal of Drug Targeting. 32 (3): 287–299. doi:10.1080/1061186X.2024.2309575. PMID 38252035.
  13. ^ Cite error: The named reference Iijima2 was invoked but never defined (see the help page).
  14. ^ Cite error: The named reference Bethune was invoked but never defined (see the help page).
  15. ^ Cite error: The named reference Thess was invoked but never defined (see the help page).

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