Tetrahedral molecular geometry

Tetrahedral molecular geometry
ExamplesCH4, MnO
4
Point groupTd
Coordination number4
Bond angle(s)≈ 109.5°
μ (Polarity)0

In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are cos−1(−13) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane (CH4)[1][2] as well as its heavier analogues. Methane and other perfectly symmetrical tetrahedral molecules belong to point group Td, but most tetrahedral molecules have lower symmetry. Tetrahedral molecules can be chiral.

  1. ^ Alger, Nick. "Angle Between 2 Legs of a Tetrahedron". Archived from the original on 2018-10-03.
  2. ^ Brittin, W. E. (1945). "Valence Angle of the Tetrahedral Carbon Atom". J. Chem. Educ. 22 (3): 145. Bibcode:1945JChEd..22..145B. doi:10.1021/ed022p145.

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