Rayon

When a solution of cellulose in cuprammonium hydroxide comes into contact with sulfuric acid, the cellulose begins to precipitate from the solution. The acid reacts with a complex compound of copper and dissolves it, and thin blue fibers of rayon are formed. After some time, the acid reacts with the complex compound and washes out the copper salts from the fibers, which become colorless.

Rayon, also called viscose[1] and commercialised in some countries as sabra silk or cactus silk,[2] is a semi-synthetic fiber[3] made from natural sources of regenerated cellulose, such as wood and related agricultural products.[4] It has the same molecular structure as cellulose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. It can be woven or knit to make textiles for clothing and other purposes.[5]

Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common solubilization methods are:

  1. ^ "Viscose CV Introduction". Swicofil.com.
  2. ^ "Weaving a Story". Franklin Till. Archived from the original on 2023-09-28.
  3. ^ "The Differences Between Synthetic, Semi-synthetic, & Natural Fibers". Retrieved 2025-05-13.
  4. ^ Kauffman, George B. (1993). "Rayon: The First Semi-Synthetic Fiber Product". Journal of Chemical Education. 70 (11): 887. Bibcode:1993JChEd..70..887K. doi:10.1021/ed070p887.
  5. ^ Krässig, Hans; Schurz, Josef; Steadman, Robert G.; Schliefer, Karl; Albrecht, Wilhelm; Mohring, Marc; Schlosser, Harald (2002). "Cellulose". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a05_375.pub2. ISBN 978-3-527-30673-2.
  6. ^ Burchard, Walther; Habermann, Norbert; Klüfers, Peter; Seger, Bernd; Wilhelm, Ulf (1994). "Cellulose in Schweizer's Reagent: A Stable, Polymeric Metal Complex with High Chain Stiffness". Angewandte Chemie International Edition in English. 33 (8): 884–887. doi:10.1002/anie.199408841.
  7. ^ Nijhuis, Michelle (June 2009). "Bamboo Boom: Is This Material for You?". Scientific American. Vol. 19, no. 2. pp. 60–65. Bibcode:2009SciAm..19f..60N. doi:10.1038/scientificamericanearth0609-60 (inactive 3 May 2025). Retrieved 2025-05-19.{{cite magazine}}: CS1 maint: DOI inactive as of May 2025 (link)
  8. ^ Swan, Norman; Blanc, Paul (20 February 2017). "The Health Burden of Viscose Rayon". Radio National. Retrieved 2025-05-21.
  9. ^ "Regenerated Cellulose by the Lyocell Process, a Brief Review of the Process and Properties". BioResources. 2018.
  10. ^ Tierney, John (December 2005). Kinetics of Cellulose Dissolution in N-Methyl Morpholine-N-Oxide and Evaporative Processes of Similar Solutions (Thesis).

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