Manganocene

Manganocene
Names
Other names
Bis(cyclopentadienyl)manganese
Identifiers
3D model (JSmol)
ECHA InfoCard 100.149.777 Edit this at Wikidata
  • InChI=1S/2C5H5.Mn/c2*1-2-4-5-3-1;/h2*1-3H,4H2;/q2*-1;+2
    Key: LCGVCXIFXLGLHG-UHFFFAOYSA-N
  • c1[cH-]ccc1.[Mn+2].c1[cH-]ccc1
Properties
C10H10Mn
Molar mass 185.128 g·mol−1
Appearance amber solid < 159 °C, pink > 159 °C
Melting point 175 °C (347 °F; 448 K)
Boiling point 245 °C (473 °F; 518 K)
Hazards[1]
GHS labelling:
GHS02: FlammableGHS07: Exclamation mark
Danger
H228, H315, H319, H335
P210, P261, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazards (white): no code
2
2
3
Flash point 52 °C (126 °F; 325 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Manganocene or bis(cyclopentadienyl)manganese(II) is an organomanganese compound with the formula [Mn(C5H5)2]n. It is a thermochromic solid that degrades rapidly in air. Although the compound is of little utility, it is often discussed as an example of a metallocene with ionic character.[2]

  1. ^ "Bis(cyclopentadienyl)manganese". American Elements. Retrieved October 31, 2019.
  2. ^ Layfield, Richard A. (2008). "Manganese(II): the black sheep of the organometallic family". Chem. Soc. Rev. 37 (6): 1098–1107. doi:10.1039/B708850G. PMID 18497923.

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