Electron hole

In physics, chemistry, and electronic engineering, an electron hole (often simply called a hole) is a quasiparticle denoting the lack of an electron at a position where one could exist in an atom or atomic lattice. Since in a normal atom or crystal lattice the negative charge of the electrons is balanced by the positive charge of the atomic nuclei, the absence of an electron leaves a net positive charge at the hole's location.

Holes in a metal^[1] or semiconductor crystal lattice can move through the lattice as electrons can, and act similarly to positively-charged particles. They play an important role in the operation of semiconductor devices such as transistors, diodes (including light-emitting diodes) and integrated circuits. If an electron is excited into a higher state it leaves a hole in its old state. This meaning is used in Auger electron spectroscopy (and other x-ray techniques), in computational chemistry, and to explain the low electron-electron scattering-rate in crystals (metals and semiconductors). Although they act like elementary particles, holes are rather quasiparticles; they are different from the positron, which is the antiparticle of the electron. (See also Dirac sea.)

In crystals, electronic band structure calculations show that electrons have a negative effective mass at the top of a band. Although negative mass is unintuitive,^[2] a more familiar and intuitive picture emerges by considering a hole, which has a positive charge and a positive mass, instead.